Hey here is an example of a Magento site where all pages (even statics like About-us) have been moved to the flat .html extension (example: http://www.topdjgear.com/about-topdjgear.html/)
In my opinion it is best to present a uniform URL structure sitewide and generally flat HTML files are a good thing although I also have worked on very successful eCommerce sites that used no file extension.
It is relatively easy in Magento to mod you static page to include the file extension, so in terms of lowest barrier, this is the route I would go.