"I accidentally manually submitted the url to google and manually in submitted it to index and that when this issue began...."
It sounds like you accidently added this URL to the index. You can follow the procedure outlined below to request Google remove the specific URL from the index:
https://support.google.com/webmasters/bin/answer.py?hl=en&answer=59819
I checked your site's structure using Screaming Frog and it does not appear that you are linking to any non-.html versions. If I perform a scan using one of your non-.html pages, it appears that it only links to itself.
Since you have the 301 redirect in place, you can choose to wait it out and Google should correct things eventually; otherwise, requesting Google remove the URL is a faster... PERMANENT process.
Good luck.
Mike