If you have moved the content elsewhere, 301 Permanent Redirect should be used, as it passes all(well most) the old pages link value e.t.c. to the new page
If it's temporarly elsewhere, 302
If it's gone for good and not coming back and theres nowhere apropriate to send people, consider 410 gone.
If you mean what status code should your missing pages/bad urls return, that should be 404, not 3XX. Redirecting the user to a 'error' page with a 301 that then returns 200 ok is a great way to have a lot of problems and little way of spotting them.