I am not aware of anyway to determine if a site has implemented Google Webmaster Tools or not, as they could have verified it with by uploading a randomly named file, or through Google Analytics. I would say if they are fairly large site and have Google Analytics (which you can determime by viewing the source code of the site) they probably have GWMT as well.
To determine if Bing Webmaster Tools are in use, you can go to http://example.com/BingSiteAuth.xml (replace the domain name) and see if the file exists. If it does, then they activated Bing Webmaster Tools. If the file does not exist, it either means that they never activated Bing Webmaster Tools, or they did and were smart enough to delete the file from their server.
Hope this helps!