Do not nofollow your social media profiles.
Adding nofollows to links does not increase your PR, it just eliminates the link juice that would have gone to those pages. Do not nofollow your own links or links to properties you manage. Only nofollow links if they are low quality sites, you have a commercial relationships with them, or they are competitors.
Linking to your social media profiles will also get them ranking higher in the search results for your brandname, which is a good thing if you maintain good social media profiles.